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DOI: | 10.2134/jeq2007.0543 |
Web URL(s): | https://dl.sciencesocieties.org/publications/jeq/articles/37/6/2221 Last checked: 11/07/2016 Access conditions: Item is within a limited-access website https://dl.sciencesocieties.org/publications/jeq/pdfs/37/6/2221 Last checked: 11/08/2016 Requires: PDF Reader Access conditions: Item is within a limited-access website |
Publication Type:
| Refereed |
Author(s): | Kalis, Erwin J. J.;
Temminghoff, Erwin J. M.;
Town, Raewyn M.;
Unsworth, Emily R.;
van Riemsdijk, Willem H. |
Author Affiliation: | Kalis, Temminghoff, and van Riemsdijk:Department of Soil Quality, Wageningen University, Netherlands; Town: School of Chemistry, Queen's University, Belfast, United Kingdom; Unsworth: Department of Environmental Science, University of Lancaster, Lancaster, United Kingdom |
Title: | Relationship between metal speciation in soil solution and metal adsorption at the root surface of ryegrass |
Section: | Technical reports: Plant and environment interactions Other records with the "Technical reports: Plant and environment interactions" Section
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Source: | Journal of Environmental Quality. Vol. 37, No. 6, November/December 2008, p. 2221-2231. |
Publishing Information: | Madison, Wisconsin: American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America |
# of Pages: | 11 |
Keywords: | TIC Keywords: Metals; Soil solution; Adsorption; Lolium perenne; Soil PH; Shoots; Root analysis; Ions; Calcium chloride; Nickel; Cadmium chloride; Zinc; Copper
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Abstract/Contents: | "The total metal content of the soil or total metal concentration in the soil solution is not always a good indicator for metal availability to plants. Therefore, several speciation techniques have been developed that measure a defined fraction of the total metal concentration in the soil solution. In this study the Donnan Membrane Technique (DMT) was used to measure free metal ion concentrations in CaCl2 extractions (to mimic the soil solution, and to work under standardized conditions) of 10 different soils, whereas diffusive gradients in thin-films (DGT) and scanning chronopotentionmetry (SCP) were used to measure the sum of free and labile metal concentrations in the CaCl2 extracts. The DGT device was also exposed directly to the (wetted) soil (soil-DGT). The metal concentrations measured with the speciation techniques are related to the metal adsorption at the root surface of ryegrass (Lolium perenne L.) to be able to subsequently predict metal uptake. In most cases the metal adsorption related pH-dependently to the metal concentrations measured by DMT, SCP, and DGT in the CaCl2 extract. However, the relationship between metal adsorption at the root surface and the metal concentrations measured by the soil-DGT was not - or only slightly - pH dependent. The correlations between metal adsorption at the root surface and metal speciation detected by different speciation techniques allow discussion about rate limiting steps in biouptake and the contribution of metal complexes to metal bioavailability." |
Language: | English |
References: | 38 |
Note: | Tables Graphs |
| ASA/CSSA/SSSA Citation (Crop Science-Like - may be incomplete): Kalis, E. J. J., E. J. M. Temminghoff, R. M. Town, E. R. Unsworth, and W. H. van Riemsdijk. 2008. Relationship between metal speciation in soil solution and metal adsorption at the root surface of ryegrass. J. Environ. Qual. 37(6):p. 2221-2231. |
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| DOI: 10.2134/jeq2007.0543 |
| Web URL(s): https://dl.sciencesocieties.org/publications/jeq/articles/37/6/2221 Last checked: 11/07/2016 Access conditions: Item is within a limited-access website https://dl.sciencesocieties.org/publications/jeq/pdfs/37/6/2221 Last checked: 11/08/2016 Requires: PDF Reader Access conditions: Item is within a limited-access website |
| MSU catalog number: b2225072a |
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