Full TGIF Record # 22870
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Web URL(s):https://dl.sciencesocieties.org/publications/jeq/pdfs/21/1/JEQ0210010121
    Last checked: 12/12/2016
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Publication Type:
i
Refereed
Author(s):Kempton, Houston; Davis, Andy; Olsen, Roger
Author Affiliation:PTI Environmental Services, Colorado; PTI Environmental Serivces, Colorado; Camp, Dresser and McKee, Colorado
Title:Remediation of solvent-contaminated soils by aeration
Source:Journal of Environmental Quality. Vol. 21, No. 1, January-March 1992, p. 121-128.
Publishing Information:Madison, Wisconsin: American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
Keywords:TIC Keywords: Solvents; Soil contamination; Aeration
Abstract/Contents:A bench-scale box test was performed to evaluate the feasibility of rototilling to remediate excavated soils contaminated with tetrachloroethylene (PCE), trichloroethylene (TCE), and 1,1,1-trichloroethane (1,1,1-TCA). Two clay-rich soils (A and B) containing 0.15% organic C and different concentrations of the target analytes were placed in 15-cm thick layers under a 10 km h-1 wind, tilled daily, and samples collected and analyzed periodically. Soil A (25 000 u[mu]g kg-1 PCE) lost 80% after 24 h and 97% after 407 h. Soil B (8881 u[mu]g kg-1 PCE) lost 29% after 24 h and 92% after 407 h. Initial TCE and 1,1,1-TCA concentrations ranged from 793 to 1570 u[mu]g kg-1. Relative volatilization loss rates were similar to that of PCE. The average volaitilization half-lives of the solvents were 1.2 d for PCE, 0.58 d for TCE, and 0.64 d for 1,1,1-TCA. Removal of the analytes slowed considerably after 200 h, with a small (10%) amount of each analyte retained in refractory sites. Residual solvent concentrations in soils A and B after 407 h were 835 and 719 u[mu]g kg-1 PCE, 38 and 95 u[mu]g kg-1 TCE, and 21 and 31 u[mu]g kg-1 1,1,1-TCA. Simulations of volatilization using the pesticide root zone model (PRZM) accurately predicted the loss of PCE, TCE, and 1,1,1-TCA over the first 24 h when most of the solvent volatized, but the model overpredicted contaminant losses at longer durations when remnant soil concentrations were less than six times the concentration bound to refractory sites.
Language:English
References:23
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ASA/CSSA/SSSA Citation (Crop Science-Like - may be incomplete):
Kempton, H., A. Davis, and R. Olsen. 1992. Remediation of solvent-contaminated soils by aeration. J. Environ. Qual. 21(1):p. 121-128.
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Web URL(s):
https://dl.sciencesocieties.org/publications/jeq/pdfs/21/1/JEQ0210010121
    Last checked: 12/12/2016
    Requires: PDF Reader
    Notes: Item is within a limited-access website
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